Junior research group Theoretical Chemistry

Dassia Egorova

Ultrafast Dynamics and Time-resolved Spectroscopy

Research project

Vibronic effects in ultrafast dynamics and spectroscopy

Coupling of electronic and vibrational (nuclear) motion, known as vibronic coupling, is almost inevitable once several electronic states are involved in the dynamics. Therefore, vibronic effects must be taken into account in all kinds of nonlinear time-resolved optical spectroscopy. We study the role of vibronic coupling in ultrafast dynamics and thoroughly investigate its influence on four-wave mixing signals, like, e.g., two-dimensional photon-echo or pump-probe techniques.

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